JiuZhou No.

Chemical Name

Structure Formula 

[α]_D²⁰

CAS Reg.No

Acronym

M.P. ℃

Abs. Config.

MF, MW

Purity HPLC

JZ-S001-1

N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'diyl]phosphoramidite

+505
(c 0.5,
CH₂Cl₂)

[443965-14-8]

(R)-SIPHOS

95-96

( R )

C₁₉H₂₀NO₂P
FW: 325.34

≥98%

JZ-S001-2

N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite

-502
(c 0.5,
CH₂Cl₂)

[443965-10-4]

(S)-SIPHOS

95-96

( S )

C₁₉H₂₀NO₂P
FW: 325.34

≥98%

JZ-S002-1

Phenyl-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphite

+216
(c 0.5,
CH₂Cl₂)

[656233-53-3]

(R)-ShiP

104-105

( R )

C₂₃H₁₉O₃P
FW: 374.37

≥98%

JZ-S002-2

Phenyl-[(S)-1,1'-spirobiindane-7,7'-diyl]-phosphite

-215
(c 0.51,
CH₂Cl₂)

[885701-71-3]

(S)-ShiP

104-105

( S )

C₂₃H₁₉O₃P
FW: 374.37

≥98%

JZ-S003-1

N-Di[(R)-1-phenylethyl]-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite

+300
(c 1.0,
CH₂Cl₂)

[500997-69-3]

(Ra,R,R)-SIPHOS-PE

98-100

( Ra,R,R )

C₃₃H₃₂NO₂P
FW: 505.59

≥98%

JZ-S003-2

N-Di[(R)-1-phenylethyl]-[(S)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite

-63.5
(c 1.0,
CH₂Cl₂)

[500997-70-6]

(Sa,R,R)-SIPHOS-PE

99-101

( Sa,R,R )

C₃₃H₃₂NO₂P
FW: 505.59

≥98%

JZ-S004-1

(R)–7,7'-bis(diphenylphosphino)-1,1'-spirobiindane

+207
(c 0.5,
CH₂Cl₂)

 [917377-74-3 ]

(R)-SDP

200-202

( R )

C₄₁H₃₄P₂
FW: 588.66

≥97%

JZ-S004-2

(S)–7,7'-bis(diphenylphosphino)-1,1'-spirobiindane

-203
(c 0.5,
CH₂Cl₂)

[528521-86-0 ]

(S)-SDP

206-208

( S )

C₄₁H₃₄P₂
FW: 588.66

≥97%

JZ-S005-1

(R)–7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane

+212
(c 0.53,
CH₂Cl₂)

[528521-87-1 ]

(R)-Tol-SDP

150-152

( R )

C₄₅H₄₂P₂
FW: 644.76

≥97%

JZ-S005-2

(S)–7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane

-221
(c 0.54,
CH₂Cl₂)

[817176-80-0 ]

(S)-Tol-SDP

150-152

( S )

C₄₅H₄₂P₂
FW: 644.76

≥97%

JZ-S006-1

(R)–7,7'-Bis[di(3,5-dimethylphenyl)phosphino]-1,1'-spirobiindane

+87.5
(c 0.53,
CH₂Cl₂)

[917377-75-4 ]

(R)-Xyl-SDP

Oil

( R )

C₄₉H₅₀P₂
FW: 700.87

≥97%

JZ-S006-2

(S)–7,7'-Bis[di(3,5-dimethylphenyl)phosphino]-1,1'-spirobiindane

-83
(c 0.53,
CH₂Cl₂)

[528521-89-3 ]

(S)-Xyl-SDP

Oil

( S )

C₄₉H₅₀P₂
FW: 700.87

≥97%

JZ-S007-1

(R)-O,O'-[7,7'-(1,1'-spirobiindan)]-tert-butylphosphonite

+456
(c 1.2,
CH₂Cl₂)

(R)-FuP-tBu

( R )

C₂₁H₂₃O₂P
FW: 338.38

≥97%
≥99%EE

JZ-S007-2

(S)-O,O'-[7,7'-(1,1'-spirobiindan)]-tert-butylphosphonite

-456
(c 1.2,
CH₂Cl₂)

[912457-08-0]

(S)-FuP-tBu

( S )

C₂₁H₂₃O₂P
FW: 338.38

≥97%
≥99%EE

JZ-S008-1

(R)-dimethylene-[7,7'-(1,1'-spiroindan)]-phenylphospholane

[α]_D²¹:+6
(c 0.5,
CH₂Cl₂)

[856407-37-9]

(R)-SITCP

148-149

( R )

C₂₅H₂₃P
FW: 354.42

≥97%
≥99%EE

JZ-S008-2

(S)-dimethylene-[7,7'-(1,1'-spiroindan)]-phenylphospholane

[α]_D²¹:-6
(c 0.5,
CH₂Cl₂)

[885701-78-0]

(S)-SITCP

148-149

( S )

C₂₅H₂₃P
FW: 354.42

≥97%
≥99%EE

JZ-S009-1

(Ra,S)-7-[4-(Benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiinane

(R,S)-Ph-Bn-SIPHOX

98-100

( Ra,S )

C₃₉H₃₄NOP
FW: 563.67

≥97%
≥99%EE

JZ-S009-2

(Sa,S)-7-[4-(Benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiinane

-227.0
(c 0.5,
CH₂Cl₂)

[913829-88-6]

(Sa,S)-Ph-Bn-SIPHOX

164-166

( Sa,S )

C₃₉H₃₄NOP
FW: 563.67

≥97%
≥99%EE

JZ-S010-1

(S,S)-7-[4-(Benzyl)oxazol-2-yl]-7'-di(3,5-ditertbutylphenyl)phosphinyl-1,1'- spirobiindane

[α]_D²⁵:
-185.6
(c 0.5,
CH₂Cl₂)

[1040274-10-9]

(S,S)-DTB-Bn-SIPHOX

159-161

(S,S)

C₅₅H₆₆NOP
FW: 788.09

≥97%
≥99%EE

JZ-S011-1

(S)-7-(4,5-Dihydrooxazol-2-yl)-7'-di(3,5-ditertbutylphenyl)phosphino-1,1'- spirobiinane

[α]_D²⁵:
-184.4
(c 0.5,
CH₂Cl₂)

[1040274-18-7]

(S)-DTB-SIPHOX

229-231

( S )

C₄₈H₆₀NOP
FW: 697.97

≥97%
≥99%EE

JZ-S012-1

(Sa,S)-7-[4-(Benzyl)oxazol-2-yl]-7-di(3,5-dimethylphenyl)phosphinyl-1,1- spirobiinane

[α]_D²⁴:
-196.8
(c 0.51,
CH₂Cl₂)

[913829-90-0]

(Sa,S)-Xyl-Bn-SIPHOX

Oil

( Sa,S )

C₄₃H₄₂NOP
FW: 619.77

≥97%
≥99%EE

JZ-S013-1

(Sa,S,S)-7,7'-bis(4'-phenyloxazol-2-yl)-1,1'-spirobiindane

-322
(c 0.5,
CH₂Cl₂)

[940880-69-3]

(Sa,S,S)-SpiroBOX

167-169

(Sa,S,S)

C₃₅H₃₀N₂O₂
FW: 510.62

≥97%

JZ-S013-2

(Ra,S,S)-7,7'-bis(4'-phenyloxazol-2-yl)-1,1'-spirobiindane

+93
(c 0.5,
CH₂Cl₂)

[890090-21-8]

(Ra,S,S)-SpiroBOX

130-132

(Ra,S,S)

C₃₅H₃₀N₂O₂
FW: 510.62

≥97%