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Overview
Even though plastics have made our lives more comfortable,
the widespread adoption of plastics accompanies various
problems relating to flammability. To comply with
the public's demands for flame retardant polymers.
Cheil has devoted itself to the development of Starex
flame retardant ABS. Even if ABS with its high impact
strength, chemical resistance and good appearance
can be used in electric and electronic components
(interior and exterior parts), its use in electric
and electronic components requires a high degree of
heat resistance as well as balanced impact resistance
and fluidity. Flame retardant grades of Starex ABS,
with its outstanding heat resistance, offers an optimized
balance of properties while minimizing the deterioration
of its original properties, which can be achieved
by adding various flame retardants. Also, with many
Starex flame retardant ABS resins to choose from,
you can select one that matches your design needs.
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Classifications
Starex flame retardant ABS can be classified into two
groups; The VH and VE-series. This is made possible
through the Cheil's advanced technology.
VH-Series
VH-seriesis the grade network with improved processability
and balanced mechanical properties.
Their properties are as follows. VH-0800 : having
excellent processability and injection moldability,
VH-0800 is the most popular 1/16" V-O rated grade
for computer monitors. VH-0806 : 1/10" V-O rated
VH-0806 grade has an improved impact strength and
heat resistance comparable to VH-0800. VH-0810 : with
improved heat resistance and flow characteristics,1/10"
V-O rated VH-0810 grade reduces production cost. VH-0850:
as 1/10" 5V, 1/16" V-O rated grade VH-0850
has a higher impact strength. VH-0853 : having a greatly
improved weather resistance,excellent heat stability,
and flammability rating of 1/10" 5V and 1/16"
V-O, this grade is recommended to use for products
with lighter colors. VT-0820 : with a V-2 rating,
this grade has a good balance of mechanical properties.
VE-Series
As a substitute for engineering plastics, the most
essential properties needed for a flame retardant
ABS are weather resistance and heat resistance.
With these characteristics, the product's marketability
and quality will be enhanced. With this in mind, the
VE-series adopts different additive system for stability
through a advanced technological process, so that
it would work better. If used with other resin grades,
thermal stability deterioration can be easily observed.
As an intermediate resin between flame retardant ABS
and engineering plastics, the VE-series provides excellent
processability and cost effectiveness in comparison
to flame retardant engineering plastic. It also displays
superior weather and heat resistance properties in
comparison to flame retardant ABS. VE-0812 : 1/10"
V-O grade with high weather resistance and heat resistance.
VE-0855 : 1/10" 5V, 1/12" V-O rated grade
with super weather resistance and high heat resistance.
VE-0856: 1/10" 5V, 1/12" V-O grade with
high weather resistance and heat resistance.
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Properties
As explained in the previous section, flame retardant
ABS may have some disadvantages compared with general
ABS except for the flame retardance. However, a careful
grade selection through the understanding of those features
will guarantee the user's maximum satisfaction.
1) Thermal stability Since the self-extinguishing
properties of flame retardant ABS may result from
the thermal decomposition of flame retardants during
burning, flame retardant ABS can have poor thermal
stability in comparison with general ABS. In particular,
since flame retardants can possibly decompose when
molded at temperature of 230oC or above, molding at
lower temperatures than required with general ABS
is recommened. Cheil Industries Inc. has developed
the technology to produce Starex flame retardant ABS
with excellent thermal stability and flame retardancy.
Starex flame retardant ABS, especially VH-0853 and
VH-0800, is useful for geometrically complex molds.
2) Weather resistance Since ABS contains butadiene
to enhance impact strength, it can be discolored if
exposed to sunlight for a longtime. And this prevents
its usefulness with such O.A. applicances as computer
monitors, printers, and photocopying machine. As one
of the leading companies in the production of ABS
resin. Cheil has made the effort to solve these problems,
and it has successfully produced a flame retardant
ABS series with excellent weather resistance. Among
the series, VH-0853, VE-0812,VE-0855 or VE- 0856 can
be the best choice for applications demanding weather
resistance.
3) Blooming and plating-out During injection molding,
flame retardants can diffuse out to the surface and
cause mold contamination. Since this phenomenon becomes
worse with darker colors, it is recommended not to
use flame retardant ABS grade resins with dark color
shades. However, blooming is not observed while using
all Starex flame retardant ABS grade exceptVH-0853.
Starex flame retardant ABS grades with their excellent
qualities allow for flexible product designs.
4) Heat resistance Heat resistance implies that the
product is not prone to deformation while being exposed
to a wide temperature range.The excellent heat resistance
of Starex flame retardant ABS makes it possible to
increase the reliability of injection molded products.
However care must be taken to select the proper grade
of Starex flame retardant ABS for final use. For cost
reduction and improved injection productivity,the
VE-series can be the best choice as an engineering
plastics substitute,while the VH-series is suitable
when processability is more important design factor
than heat resistance.
5) Flammability Generally, flammability can be rated
according to UL-94 VB standards. Cheil produces various
flame retardant ABS's with varying flammability levels
to meet the requirements of specific applications.
Cheil's Starex flame retardant ABS has obtained UL-94
flammability ratings of V-2, V-1, V-0 and 5V.
6) Flame retardants PBDE is one of the most popular
compounds used as an additive to promote the flame
retardance of plastics. There was a trend to restrict
PBDE's use as a flame retardant compound because of
the possibility that PBDE could induce toxic dioxin
or difuran derivatives at an elevated temperature
condition. Even though it has been speculated that
PBDE is not so dangerous, most electric and electronic
companies still avoid using PBDE as a flame retardant.
Starex flame retardant ABS resins do not contain such
controvertial flame retardant compounds. Therefore,
Starex flame retardant ABS can be used for exterior
applications.
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Type & Applications
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Class |
Grades |
Characteristics |
Typical
application |
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VH-0800P |
Excellent
flow |
Computer
monitors,
printers,
facsimile machines,
OA equipment,
photocopying machines |
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VH-0810
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Good
flow, Good heat
resistance 1/10" V-0
grade |
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VH-0815
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V-5
grade |
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VH-0850 |
Excellent
impact
resistance 5V grade |
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VT-0820 |
V-2
grade |
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VE-0812 |
Excellent
heat
resistance, good
weatherability, low
density, Non-blooming,
no plating-out |
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VE-0855 |
well
balanced
properties |
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VE-0856
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Excellent
weatherability
excellent heat
resistance low density,
non-blooming,
no plating-out |
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