4. Evaporation speed
Table 4. Evaporation speed comparison
NPB |
1,1,1-Trichloroethane |
Trichloroethylene |
Tetrachloroethylene |
Dichloromethane |
0.96 |
1.00 |
0.57 |
0.18 |
1.64 |
5. Thermal stability
Thermal stability data is very important
for assessment of a solvent's safety, particularly as regards
the toxicology of thermal decomposition products.
Generally thermal stability is tested by the following two
methods:
1. ARC method (Accelerating Rate Calorimetry) which determines
the decomposition temperature by measuring heat liberation.
NPB with or without stabilizer decomposes at above 226.5°C.
Bromomethane, benzene and other compounds are found by GC/MS
analysis in the decomposition products, but no bromine or
hydrogen bromide or other highly toxic compounds are detected
(see table below). Stabilizer has no significant influence
on the decomposition products of NPB.
2. Direct GC/MS analysis of the vapor of NPB heated
by nichrome resistant coil in the open air. Some oxidized
compounds are found by this method.
The table below shows the thermal decomposition products of
NPB by the above two tests.
Method I |
Method II |
propane |
propane |
isobutane |
bromomethane |
n-butane |
bromoethane |
bromomethane |
benzene |
2-methylbutane |
toluene |
pentane |
bromopropane |
bromoethane |
dipropyl ester |
C6H14 analogues |
1,3,5-trioxocycloheptane |
bromo-iso-propane |
4-bromobutan-2-ol |
hexane |
|
benzene |
|
C7H16 analogues |
|
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